I. Medina et al., EFFECT OF PACKING MEDIA ON THE OXIDATION OF CANNED TUNA LIPIDS - ANTIOXIDANT EFFECTIVENESS OF EXTRA VIRGIN OLIVE OIL, Journal of agricultural and food chemistry, 46(3), 1998, pp. 1150-1157
The effectiveness of packing media differing in the content of natural
antioxidants has been tested on Lipid oxidation occurring during tuna
canning. Extra virgin olive oil, having a high content in natural pol
yphenols, and other filling media lacking phenols (refined olive oil,
refined soybean oil, and brine) were selected. The three oils also sho
wed different quantities of tocopherols, the highest amount being dete
cted in refined soybean ail. Different rates of oxidation were observe
d among the four media after thermal processing and storage of tuna ca
ns; extra virgin olive oil showed a potential antioxidant activity on
fish lipids. The verified antioxidant ability may be attributed to the
solubilization of hydrophilic phenols into the water-muscle interface
. The phenolic composition from extra virgin olive oil studied by reve
rsed-phase HPLC showed a marked change after fish processing, thus sug
gesting phenol decompositions and strong interactions between oil phen
ols and fish muscle components. The aqueous environment built by brine
made fish lipids more prone to oxidation, presumably due to the accum
ulation of unsaturated fatty acids at the ail-water interface.