Anomalies have been observed in photoluminescence (PL) of pure-Ge/Si t
ype-II coupled quantum wells (II-CQWs). Although the II-CQWs (L-Ge = 1
.5 ML) showed clear energy red-shift with decreasing Si spacer thickne
ss (Lsi) due to interwell coupling of the hale wavefunction, an anomal
ous energy lowering was observed for smaller L-Si (less than or equal
to 6 Angstrom). Moreover, PL intensity of the II-CQWs increased linear
ly with increasing excitation power, as opposed to a sublinear increas
e in type-II QWs due to exciton localization at the interfaces. These
results seem to be the result of enhanced electron capture by the II-C
QW potential profile. Furthermore, correlation of thickness fluctuatio
n among the layers was observed by high-resolution transmission electr
on microscopy, which may be connected to the PL anomalies.