EXCLUSIVE CIS-1,4-ADDITION REACTION IN THE BROMINATION OF 2,5-BIS(TRIMETHYLSILYL)THIOPHENE MONOOXIDE

Authors
ZHANG SZ SATO S HORN E FURUKAWA N
Citation
Sz. Zhang et al., EXCLUSIVE CIS-1,4-ADDITION REACTION IN THE BROMINATION OF 2,5-BIS(TRIMETHYLSILYL)THIOPHENE MONOOXIDE, Heterocycles, 48(2), 1998, pp. 227-234
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
48
Issue
2
Year of publication
1998
Pages
227 - 234
Database
ISI
SICI code
0385-5414(1998)48:2<227:ECRITB>2.0.ZU;2-C
Abstract
2,5-Bis(trimethylsilyl)thiophene monooxide (1) underwent a 1,4-additio n reaction with Br-2 to give stereospecifically 2,5-bis(trimethylsilyl )-2,5-cis-dibromothiolene monooxide (2) in quantitative yield.