Masses and couplings of negative parity baryons are studied in the QCD
sum rule, A technique to single out tile negative-parity spectrum is
proposed. The quark condensates that break the chiral symmetry cause m
ass splittings between the ground state and negative parity baryons, s
uggesting that they form parity doublet. (In the flavor singlet spectr
a the negative parity baryon is the lowest state.) We also compute the
pi NN coupling and found that it vanishes in the soft pion limit due
to the chiral structure of the interpolating field.