1,6-PI-ELECTROCYCLIZATION OF 3-VINYL-FUNCTIONALIZED N,N'-DIMETHYL-2,2'-BISINDOLYL - SOME ANALYSIS OF THE EDUCT TRANSFORMATION PROCESS

Authors
Citation
U. Pindur et Ys. Kim, 1,6-PI-ELECTROCYCLIZATION OF 3-VINYL-FUNCTIONALIZED N,N'-DIMETHYL-2,2'-BISINDOLYL - SOME ANALYSIS OF THE EDUCT TRANSFORMATION PROCESS, Journal of heterocyclic chemistry, 35(1), 1998, pp. 97-101
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0022152X
Volume
35
Issue
1
Year of publication
1998
Pages
97 - 101
Database
ISI
SICI code
0022-152X(1998)35:1<97:1O3N>2.0.ZU;2-O
Abstract
The thermally and photochemically induced 1,6-pi-electrocyclization re action of 3-vinyl-functionalized N,N'-dimethyl-2,2'-bisindolyls 4 has been analysed and some reactivity aspects are presented. On the basis of time dependent H-1 nmr and uv spectroscopic measurements the educt transformations can be observed in detail. Some results of the isomeri zation process of the educts are also given.