We study the Green kernel at infinity for random walks and diffusions
on the solvable Lie groups which are semi-direct extensions of simply
connected nilpotent groups by an abelian group isomorphic to R-d. We n
otice that Markov processes on Hadamard homogeneous Riemannian manifol
ds can be seen as random walks of the above type if their transition k
ernel commutes with isometries (e.g. Brownian Motion). This leads to a
description of the Martin topology on the Poisson boundary and, in th
e case of Riemannian symmetric spaces, to precise asymptotics for the
Green kernel and the Martin kernel in the regular directions for 'disc
rete brownian motions'.