UNPRECEDENTED CONVERSION OF BENZYLIDENEANILINES INTO ARYL ISOCYANIDESPROMOTED BY A LOW-VALENT MOLYBDENUM COMPLEX - X-RAY STRUCTURE OF TRANS-[MO(CNPH)(N-2)(PH2PCH2CH2PPH2)(2)]

Authors
NAKAMURA G HARADA Y ARITA C SEINO H MIZOBE Y HIDAI M
Citation
G. Nakamura et al., UNPRECEDENTED CONVERSION OF BENZYLIDENEANILINES INTO ARYL ISOCYANIDESPROMOTED BY A LOW-VALENT MOLYBDENUM COMPLEX - X-RAY STRUCTURE OF TRANS-[MO(CNPH)(N-2)(PH2PCH2CH2PPH2)(2)], Organometallics, 17(6), 1998, pp. 1010-1012
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
6
Year of publication
1998
Pages
1010 - 1012
Database
ISI
SICI code
0276-7333(1998)17:6<1010:UCOBIA>2.0.ZU;2-1
Abstract
The molybdenum dinitrogen complex trans-[Mo(N-2)(2)(dppe)(2)] (dppe = Ph2PCH2CH2PPh2) reacts with an excess of PhCH = NAr (Ar = Ph, p-MeC6H4 , p-MeOC6H4) in benzene at reflux under N-2 to give novel isocyanide-d initrogen complexes, trans-[Mo(CNAr)(N-2)(dppe)(2)] (5), in moderate y ield. An X-ray diffraction study of 5a (Ar = Ph) is reported.