METAL - METAL-BOND-ASSISTED SUBSTITUTION-REACTION OF A HETEROBIMETALLIC PHOSPHIDO-BRIDGED MO-FE COMPLEX

Authors
HSIAO SM SHYU SG
Citation
Sm. Hsiao et Sg. Shyu, METAL - METAL-BOND-ASSISTED SUBSTITUTION-REACTION OF A HETEROBIMETALLIC PHOSPHIDO-BRIDGED MO-FE COMPLEX, Organometallics, 17(6), 1998, pp. 1151-1154
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
6
Year of publication
1998
Pages
1151 - 1154
Database
ISI
SICI code
0276-7333(1998)17:6<1151:M-MSOA>2.0.ZU;2-G
Abstract
The heterobimetallic phosphido-bridged complexes CpMo(CO)(2)(mu-PPh2)F e(CO)(4) (1) and CpMo(CO)(3)(mu-PPh2)Fe(CO)(4) (2) were prepared by th e reaction of CpMo(CO)(3)PPh2 with Fe-2(CO)(9). The reaction between 1 and Lewis bases L (L = P(OMe)(3), PPh2H, PPh3) at ambient temperature s produced CpMo(CO)(2)(mu-PPh2)Fe(CO)(3)(L) (3) with L regiospecifical ly coordinated to Fe. However, 2 did not react with L under similar co nditions.