DOUBLE INSERTION OF CARBON-DISULFIDE INTO PB-S BONDS OF LEAD(II) BIS(ARENETHIOLATE) - SYNTHESIS AND CRYSTAL-STRUCTURE OF LEAD(II) BIS(ARYL TRITHIOCARBONATE)

Authors
KANO N TOKITOH N OKAZAKI R
Citation
N. Kano et al., DOUBLE INSERTION OF CARBON-DISULFIDE INTO PB-S BONDS OF LEAD(II) BIS(ARENETHIOLATE) - SYNTHESIS AND CRYSTAL-STRUCTURE OF LEAD(II) BIS(ARYL TRITHIOCARBONATE), Organometallics, 17(6), 1998, pp. 1241-1244
Citations number
52
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
6
Year of publication
1998
Pages
1241 - 1244
Database
ISI
SICI code
0276-7333(1998)17:6<1241:DIOCIP>2.0.ZU;2-E
Abstract
The first lead(II) bis(aryl trithiocarbonate) compounds, (ArSCS2)(2)Pb (2a, Ar = Bbt (Bbt = 2,6-bis-[bis yl)methyl]-4-[tris(trimethylsilyl)m ethyl]-phenyl); 2b, Ar = Tbt (Tbt = 2,4,6-tris[bis(trimethylsilyl)-met hyl]phenyl)), were obtained by reaction of the corresponding Lead(ll) bis(arenethiolate) species, (ArS)2Pb: (1) with carbon disulfide. The c rystal structure of 2a . CH2Cl2 was established by X-ray crystallograp hic analysis. The formation of 2 can be rationalized in terms of doubl e insertion of carbon disulfide into two lead-sulfur bonds of 1.