E. Shabanova et al., C-13 NMR INVESTIGATIONS OF SPIN-LATTICE RELAXATION IN 99-PERCENT C-13-ENRICHED DIAMONDS, Journal of magnetic resonance [1997], 130(1), 1998, pp. 8-17
Citations number
29
Categorie Soggetti
Physics, Atomic, Molecular & Chemical","Biochemical Research Methods
The paper is devoted to investigations of spin-lattice relaxation proc
esses in 99% C-13-enriched diamonds. Relaxation time measurements were
performed as a function of orientation, magnetic field, and temperatu
re. Both experimental results and theoretical discussion are presented
. Multiexponential behavior of nuclear magnetization recovery was obse
rved. There was found no significant influence of the diamond orientat
ion on the nuclear spin-lattice relaxation. The field dependence of th
e spin-lattice relaxation time was found to be proportional to the sec
ond power of the magnetic field. The temperature measurements showed a
weak increase of the spin-lattice relaxation time with decreasing tem
perature. Possible mechanisms of impurity relaxation are considered an
d compared with the experimental data. (C) 1998 Academic Press.