PALLADIUM-CATALYZED ALKOXYCARBONYLATION OF ARYLIODONIUM AND ALKENYLIODONIUM SALTS

Citation
Sk. Kang et al., PALLADIUM-CATALYZED ALKOXYCARBONYLATION OF ARYLIODONIUM AND ALKENYLIODONIUM SALTS, Journal of the Chemical Society. Perkin transactions. I, (5), 1998, pp. 841-842
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0300922X
Issue
5
Year of publication
1998
Pages
841 - 842
Database
ISI
SICI code
0300-922X(1998):5<841:PAOAAA>2.0.ZU;2-B
Abstract
The palladium-catalyzed carbonylation of diaryliodonium tetrafluorobor ates and tosylates (toluene-p-sulfonates) in the presence of methanol and phenol afforded aromatic esters at room temperature under one atmo sphere of carbon monoxide. However, carbonylation of diaryliodonium tr iflates and bromides in methanol afforded 4-iodophenyl-substituted met hyl esters.