ASYMMETRIC-SYNTHESIS OF (2R,4R,5S)-TETRAHYDROPSEUDODISTOMIN AND STEREOISOMERS BY CYCLOADDITION OF NITRONE TO VINYLGLYCINOL

Authors
KIGUCHI T IKAI M SHIRAKAWA M FUJIMOTO K NINOMIYA I NAITO T
Citation
T. Kiguchi et al., ASYMMETRIC-SYNTHESIS OF (2R,4R,5S)-TETRAHYDROPSEUDODISTOMIN AND STEREOISOMERS BY CYCLOADDITION OF NITRONE TO VINYLGLYCINOL, Journal of the Chemical Society. Perkin transactions. I, (5), 1998, pp. 893-899
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
5
Year of publication
1998
Pages
893 - 899
Database
ISI
SICI code
0300-922X(1998):5<893:AO(AS>2.0.ZU;2-Q
Abstract
Cycloaddition of the nitrone, derived from tetradecanal, to vinylglyci nol provides an asymmetric synthesis of both (2R,4R,5S)-tetrahydropseu dodistomin and all the stereoisomers of the racemic tetrahydropseudodi stomins.