Citation
Mr. Maurya et al., RUTHENIUM(II) HYDRIDE COMPLEXES OF S-METHYLDITHIOCARBAZATES, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 36(12), 1997, pp. 1058-1062
Citations number
16
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical
ISSN journal
03764710
→ ACNP
Volume
36
Issue
12
Year of publication
1997
Pages
1058 - 1062
Database
ISI
SICI code
0376-4710(1997)36:12<1058:RHCOS>2.0.ZU;2-X
Abstract
Reactions of [RuHCl(CO)(PPh3)(3)] and [RuH2(CO)(PPh3)(3)] with schiff
bases (HL) derived from S-methyldithiocarbazate and pyridine-2-aldehyd
e, 2-acetylpyridine, thiophene-2-aldehyde, 2-acetylthiophene and furan
-2-aldehyde lead to the formation of neutral complexes of the type [Ru
X(CO)(PPh3)(2)L] (X = H or Cl). The probable stereochemistries of the
complexes have been established on the basis of elemental analysis, IR
, H-1 and C-13 NMR studies. The triphenylphosphines an trans leaving C
O and H or Cl cis to each other in the complexes.