I. Echarri et al., MULTIVARIATE-ANALYSIS APPLIED TO THE STUDY OF THE DISTRIBUTION OF CHLOROBIPHENYLS (CBS), INCLUDING THE NON-ORTHO-CBS, IN FISH AND SEA MAMMALS, Analyst, 123(3), 1998, pp. 421-427
Twenty-one individual chlorobiphenyls (CBs), including the most toxic
non-ortho-CBs, were determined in 52 samples of sea mammals, harbour p
orpoise (Phoceana phoceana), dabs (Limanda limanda), seals (Phoca vitu
lina) and dolphins (Tursiops truncatus). The toxic non-ortho-CBs and m
ono-ortho-CBs were isolated from the di-and tri-ortho-CBs using a pyre
nylsilica HPLC column prior to the final determination by GC with elec
tron-capture detection, The distribution of the CBs in the different s
pecies mere studied by principal component analysis, Separations of ma
les and females, young and adult individuals and the different species
of sea mammals were obtained based on the degree of accumulation of C
Bs.