STRUCTURAL-PROPERTIES OF LI1-TEMPERATURE(3V3O8 UPON LITHIUM INSERTIONAT AMBIENT AND HIGH)

Authors
KAWAKITA J KATAYAMA Y MIURA T KISHI T
Citation
J. Kawakita et al., STRUCTURAL-PROPERTIES OF LI1-TEMPERATURE(3V3O8 UPON LITHIUM INSERTIONAT AMBIENT AND HIGH), Solid state ionics, 107(1-2), 1998, pp. 145-152
Citations number
25
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
107
Issue
1-2
Year of publication
1998
Pages
145 - 152
Database
ISI
SICI code
0167-2738(1998)107:1-2<145:SOLULI>2.0.ZU;2-2
Abstract
Lithium insertion behaviour of lithium vanadate, Li1.2V3O8, was invest igated using both chemical and electrochemical methods at ambient and high temperature of 100 degrees C. Additional Li+ ions up to Li4V3O8 w ere accommodated under 2.5 V at 100 degrees C. Each of the cell parame ters changed linearly in the single-phase region of x < 2.0 in Li1+xV3 O8. A constant value was observed in the two-phase region of 2.0 < x < 3.0. Further lithium insertion beyond x > 3.2 lead to an increase in cell volume of the host structure.