B-FRAME SUPPORTED BIMETALLICS - [(PME(2)PH)(2)PTB9H11RU(ETA(6)-PR-ISO,C6H4ME)] AND [(PME(2)PH)(2)PTB9H9RU(ETA(6)-PR-ISO,C6H4ME)] - AN INTERESTING PAIR OF ELECTRON-DEFICIENT NIDO AND CLOSO GEOMETRIES

Authors
KIM YH COOKE PA GREATREX R KENNEDY JD THORNTONPETT M
Citation
Yh. Kim et al., B-FRAME SUPPORTED BIMETALLICS - [(PME(2)PH)(2)PTB9H11RU(ETA(6)-PR-ISO,C6H4ME)] AND [(PME(2)PH)(2)PTB9H9RU(ETA(6)-PR-ISO,C6H4ME)] - AN INTERESTING PAIR OF ELECTRON-DEFICIENT NIDO AND CLOSO GEOMETRIES, Journal of organometallic chemistry, 550(1-2), 1998, pp. 341-345
Citations number
43
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
550
Issue
1-2
Year of publication
1998
Pages
341 - 345
Database
ISI
SICI code
0022-328X(1998)550:1-2<341:BSB-[>2.0.ZU;2-7
Abstract
Ph)(2)-9-(eta(6)-(PrC6H4Me)-Pr-iso)-7,9-PtRuB9H11] has a formal close Wadian cluster-electron count, but a nido geometry, whereas -(PrC6H4Me )-Pr-iso)-4,4-(PMe2Ph)(2)-1-4-RuPtB9H9], which does have a close geome try, has a formal sub-close cluster electron count; both compounds are formed in the reaction between [6-(eta(6)-(PrC6H4Me)-Pr-iso)-nido-6 R uB9H13], KH and [PtCl2(PMe2Ph)(2)]. (C) 1998 Elsevier Science S.A.