9,10-DIMETALLATRIPTYCENES OF GROUP-14 - A STRUCTURAL STUDY

Authors
DAM MA DEKANTER FJJ BICKELHAUPT F SMEETS WJJ SPEK AL FORNIESCAMER J CARDIN C
Citation
Ma. Dam et al., 9,10-DIMETALLATRIPTYCENES OF GROUP-14 - A STRUCTURAL STUDY, Journal of organometallic chemistry, 550(1-2), 1998, pp. 347-353
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
550
Issue
1-2
Year of publication
1998
Pages
347 - 353
Database
ISI
SICI code
0022-328X(1998)550:1-2<347:9OG-AS>2.0.ZU;2-#
Abstract
From ortho-phenylenemagnesium (1), 9-phenyl-9-germa-10-silatriptycene (5) was prepared via a simple one pot procedure. The previously prepar ed 9-methyl-10-phenyl-9,10-digermatriptycene (4) and 5 are the first g ermanium-containing 9,10-dimetallatriptycenes to be structurally chara cterised. The availability of these structural data allows a comparati ve discussion of 9,10-dimetallatriptycenes of Group 14. (C) 1998 Elsev ier Science B.V.