THE METALATION OF IMINO(TRIPHENYL)PHOSPHORANE BY ETHYLMAGNESIUM CHLORIDE - THE SYNTHESIS, ISOLATION AND X-RAY STRUCTURE OF [PH3P=NMGCL.O=P(NME2)(3)](2)

Authors
BATSANOV AS BOLTON PD COPLEY RCB DAVIDSON MG HOWARD JAK LUSTIG C PRICE RD
Citation
As. Batsanov et al., THE METALATION OF IMINO(TRIPHENYL)PHOSPHORANE BY ETHYLMAGNESIUM CHLORIDE - THE SYNTHESIS, ISOLATION AND X-RAY STRUCTURE OF [PH3P=NMGCL.O=P(NME2)(3)](2), Journal of organometallic chemistry, 550(1-2), 1998, pp. 445-448
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
550
Issue
1-2
Year of publication
1998
Pages
445 - 448
Database
ISI
SICI code
0022-328X(1998)550:1-2<445:TMOIBE>2.0.ZU;2-#
Abstract
Imino(triphenyl)phosphorane, Ph3P=NH 1a, is metallated by ethylmagnesi um chloride to give the N-magnesioiminophosphorane complex [Ph3P=NMgCl . O=P(NMe2)(3)](2) 4, whose X-ray structure has been determined. (C) 1998 Elsevier Science S.A.