OXIDATION OF ALLYL ALCOHOL BY ALKALINE PERIODATE IN THE PRESENCE OF MICRO-AMOUNTS OF PALLADIUM(II)

Authors
HIREMATH GA TIMMANAGOUDAR PL NANDIBEWOOR ST
Citation
Ga. Hiremath et al., OXIDATION OF ALLYL ALCOHOL BY ALKALINE PERIODATE IN THE PRESENCE OF MICRO-AMOUNTS OF PALLADIUM(II), Journal of physical organic chemistry, 11(1), 1998, pp. 31-35
Citations number
19
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Journal of physical organic chemistry → ACNP
ISSN journal
08943230
Volume
11
Issue
1
Year of publication
1998
Pages
31 - 35
Database
ISI
SICI code
0894-3230(1998)11:1<31:OOAABA>2.0.ZU;2-U
Abstract
The oxidation of allyl alcohol by alkaline species of periodate, H2IO6 3-, was found to be catalysed by micro amounts of Pd(II) in 0.2 mol dm (-3) alkali solution. The active species of the catalyst was found to be PdCl+. A mechanism involving the interaction of the catalyst and su bstrate in prior equilibria leading to the formation of a pi-complex i s proposed and the rate is derived. (C) 1998 John Wiley & Sons, Ltd.