K. Richter et al., ANISOTROPIC PATTERNING OF COPPER-LAMINATED POLYIMIDE FOILS BY PLASMA-ETCHING, Surface & coatings technology, 97(1-3), 1997, pp. 481-487
The aim of this study was to optimize a plasma etching process for the
anisotropic patterning of copper-laminated polyimide foils. Vertical
edges and minimal mask undercut should be achieved at an acceptable et
ch rate. The experiments included reactive ion etching (RIE) in a RIE
parallel plate reactor and plasma etching in a reactor with a slot ant
enna microwave plasma source. The influence of process gas pressure, C
F4-/O-2-ratio, gas-flow rates, bias voltage and supplied power was inv
estigated on both reactors. Thermal stress of the foils during plasma
treatment caused by ion bombardement, exothermic chemical surface reac
tions and an insufficient thermal coupling of the polymer foils to the
cooled substrate holder was also investigated. From the results, proc
ess parameters were found for anisotropic patterning of copper-laminat
ed polyimide foils by plasma etching. Vias with diameters down to 25 m
u m in 50-mu m thick foils could be etched. The etch rate ratios obtai
ned (ERvertical/ERlateral) were >5 and minimal mask underetching was a
pproximate to 6.2 mu m. Therefore the achieved anisotropy a (a=1-ERlat
/ERvert) was greater than or equal to 0.8. (C) 1997 Elsevier Science S
.A.