2 NEW CATION-RADICAL BIS(ETHYLENEDITHIO)TETRASELENAFULVALENE (BETS) SALTS, ALPHA-(BETS)(6)BI3CL12-CENTER-DOT-PHCL AND (BETS)(2)BI2CL8 - SYNTHESIS, STRUCTURE AND CONDUCTING PROPERTIES - FIRST CHARACTERIZATION OF THE NEW TRINUCLEAR ANION [BI3CL12](3-)

Authors
KUSHCH ND DYACHENKO OA GRITSENKO VV CASSOUX P FAULMANN C KOBAYASHI A KOBAYASHI H
Citation
Nd. Kushch et al., 2 NEW CATION-RADICAL BIS(ETHYLENEDITHIO)TETRASELENAFULVALENE (BETS) SALTS, ALPHA-(BETS)(6)BI3CL12-CENTER-DOT-PHCL AND (BETS)(2)BI2CL8 - SYNTHESIS, STRUCTURE AND CONDUCTING PROPERTIES - FIRST CHARACTERIZATION OF THE NEW TRINUCLEAR ANION [BI3CL12](3-), Journal of the Chemical Society. Dalton transactions, (4), 1998, pp. 683-688
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
4
Year of publication
1998
Pages
683 - 688
Database
ISI
SICI code
0300-9246(1998):4<683:2NCB(S>2.0.ZU;2-8
Abstract
Two new radical cation salts, (BETS)(6)Bi3Cl12. PhCl 1 and (BETS)(2)Bi 2Cl8 2, where BETS is bis(ethylenedithio)tetraselenafulvalene, have be en obtained and their structures and conducting properties studied. Sa lt 1 has a layered structure, consisting of radical cation layers of t he a type, and segregated anion sheets containing discrete [Bi3Cl12](3 -) trinuclear anions and PhCl solvent molecules. It is metallic down t o 180 K. The crystal structure of salt 2 consists of stacks of BETS ra dical cations, with polymeric [(Bi2Cl8)(n)](2n-) anion chains arranged in a chessboard fashion. The compound 2 exhibits semiconducting prope rties.