HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF ALKALINE-EARTH METAL-SALTS OF BENZENE-1,3,5-TRICARBOXYLIC ACID

The reaction of M-II acetate (M = Sr or Ba) with benzene-1,3,5-tricarb oxylic acid (H(3)btc) yielded crystals of formulae [M(Hbtc)(H2O)(2)]. 0.5H(2)O. These compounds are isostructural as shown by X-ray single-c rystal analysis and by X-ray powder diffraction patterns. The structur es consist of alternating layers of parallel Hbtc anions and cations s tacked along the c axis. The metal ions are co-ordinated by two bident ate carboxylate groups, three monodentate carboxylate groups and two w ater molecules giving an overall co-ordination number of nine. Heating liberates 2.5 water molecules per formulae unit to give M(Hbtc) which can reversibly bind water reforming [M(Hbtc)(H2O)(2)]. 0.5H(2)O.