Jg. Han et al., THE EFFECT OF ARC ION PRE-BOMBARDMENT ON THE IMPACT FAILURE OF TIN COATING ON CO-WC, Surface & coatings technology, 98(1-3), 1998, pp. 991-996
Co-WC is increasingly used for precision dies and punches in semicondu
ctor assembly process. The enhancement of impact resistance of hard la
yer coatings on Co-WC dies and punches is crucial for the application
of hard coatings such as TiN. In this study, Co-WC has been deposited
with a TiN film after Ti bombardment at various bias voltages of 0-750
V using the cathodic are ion plating process. The surfaces' etching m
orphology and the temperature increase upon pre-bombardment with Ti io
n onto Co-WC were evaluated by SEM and in-situ monitoring, respectivel
y. The increase of bias voltage over 500 V significantly induced selec
tive etching of Co and enhanced the substrate temperature higher than
300 degrees C in 10 min, thereby promoting the formation of a dense Ti
N film onto it. The prior etching of the surface by Ti ion bombardment
with a high bias voltage was very effective in improving the adhesion
of the TiN film on Co-WC and therefore reduced plastic deformation an
d crack density around the indentation area in a Rockwell C indentatio
n test. The impact failure of a TiN coating on Co-WC could be conseque
ntly reduced under loads up to 150 N. (C) 1998 Elsevier Science S.A.