CO OXIDATION ON SMOOTH AND HIGH AREA PT, PT-RU AND PT-SN ELECTRODES

Citation
Y. Morimoto et Eb. Yeager, CO OXIDATION ON SMOOTH AND HIGH AREA PT, PT-RU AND PT-SN ELECTRODES, Journal of electroanalytical chemistry [1992], 441(1-2), 1998, pp. 77-81
Citations number
25
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
441
Issue
1-2
Year of publication
1998
Pages
77 - 81
Database
ISI
SICI code
Abstract
The electrochemical oxidation of COad was investigated on smooth and h igh area platinum, platinum-tin and platinum-ruthenium electrodes. On high area platinum, COad was classified into two types by their oxidat ion potentials: an easily oxidized one and one which is hard to oxidiz e. Pt-Ru was found to promote the oxidation of the latter, whereas Pt- Sn did the same for the former. The ternary system, Pt-Ru-Sn, showed e ven higher catalytic activity for COad oxidation than the binary syste ms. (C) 1998 Elsevier Science S.A.