SYNTHESIS AND CONFIGURATIONAL ANALYSIS OF PHOSPHONATE CAVITANDS

Authors
JACOPOZZI P DALCANALE E SPERA S CHRISSTOFFELS LAJ REINHOUDT DN LIPPMANN T MANN G
Citation
P. Jacopozzi et al., SYNTHESIS AND CONFIGURATIONAL ANALYSIS OF PHOSPHONATE CAVITANDS, Perkin transactions. 2, (3), 1998, pp. 671-677
Citations number
10
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
3
Year of publication
1998
Pages
671 - 677
Database
ISI
SICI code
0300-9580(1998):3<671:SACAOP>2.0.ZU;2-5
Abstract
Synthesis, separation and configurational analysis of phosphonated and partially phosphonated cavitands derived from resorcinarenes are desc ribed, The configuration of all diastereomers has been elucidated by t heir H-1, P-31 NMR spectra and C-13 relaxation times. In all cases the course of the bridging reaction favours the formation of the sterical ly more crowded stereoisomers having the P=O groups oriented outward w ith respect to the cavity.