RESOLUTION OF SIMULTANEOUS KINETIC SPECTROPHOTOMETRIC PROCESSES BY THE FULL-TIME SCALE TECHNIQUE IN THE FOURIER DOMAIN

The full-time scale technique in the Fourier domain was studied for re solution of simultaneous kinetic spectrophotometric processes. Two pro grams, SPGRKIT and SPGRFTQ, were designed to perform kinetic simulatio n and resolution of simultaneous kinetic processes. The method made us e of full kinetic information and matrix data processing. Data reducti on and optimization were performed using principal-components analysis and Fourier transformation. Experimental results showed the method to be successful for both simulated and experimental data. (C) 1998 Acad emic Press.