Within the past several years, advances in high-resolution electron en
ergy loss spectroscopy (HREELS) have permitted the application to incr
easingly complex systems, ''technical surfaces'', which depart from we
ll-characterized, smooth, single-crystal surfaces. These developments
have tracked a series of improvements in instrumentation, with present
generation spectrometers exhibiting limiting energy resolution below
1 meV at relatively high detector currents (10 pA, direct beam). This
paper addresses recent progress in two of these areas: polymer surface
s and model-supported catalysts.