I. Pak et al., A COMBINED ABSORPTION-WAVELENGTH MODULATION TECHNIQUE FOR DIODE-LASERSPECTROSCOPY OF VANDERWAALS COMPLEXES IN A PULSED PLANAR JET, Review of scientific instruments, 68(4), 1997, pp. 1668-1674
A tunable diode laser spectrometer modified for the investigation of m
olecular gases and van der Waals complexes in a supersonic jet is desc
ribed. Simply constructed, reliable pulsed sources with 15 mu m X (7-4
0 mm) slits were used at a repetition rate of the order of 100 Hz for
the cooling of gases and for the formation of complexes. A double modu
lation technique based on a simultaneous modulation of the jet and a 1
0 kHz wavelength modulation of the diode laser enabled measurements of
absorbances 1.3 X 10(-5) (3 X 10(-5) in relative absorption) at opera
ting: conditions corresponding to 1 s output time constant of the regi
stration system. While type multireflection optics enlarged the absorp
tion path of the laser radiation through the jet by 16 times. New spec
tra of the van der Waals complexes Ar-CH4 and Kr-CH4 in the 7 mu m reg
ion are presented in order to show the characteristics of the spectrom
eter. The final resolution in the recorded spectra was better than 40
MHz. The relational temperature of the complexes produced by the prese
nt jet source was 7-10 K, which could be compared to the 13 K excitati
on temperature measured for the two lowest rotational states of F symm
etry of the methane monomer. (C) 1997 American Institute of Physics.