CATALYTIC ASYMMETRIC OXYSELENENYLATION-ELIMINATION REACTIONS USING CHIRAL SELENIUM-COMPOUNDS

Authors
WIRTH T HAUPTLI S LEUENBERGER M
Citation
T. Wirth et al., CATALYTIC ASYMMETRIC OXYSELENENYLATION-ELIMINATION REACTIONS USING CHIRAL SELENIUM-COMPOUNDS, Tetrahedron : asymmetry, 9(4), 1998, pp. 547-550
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
4
Year of publication
1998
Pages
547 - 550
Database
ISI
SICI code
0957-4166(1998)9:4<547:CAORUC>2.0.ZU;2-4
Abstract
Only catalytic amounts of chiral selenium reagents are necessary to ac hieve a sequence of methoxyselenenylation and oxidative beta-hydride e limination of alkenes. Performing this reaction with peroxodisulfates and various metal salts led to enantiomeric excesses of up to 75%. (C) 1998 Elsevier Science Ltd. All rights-reserved.