(4,4'-DIMETHYL-2,2'-BIPYRIDINE-N,N')MANGANESE(III) ACETONITRILE SOLVATE(1 1)/

Authors
ABBOUD KA WARD BH TALHAM DR
Citation
Ka. Abboud et al., (4,4'-DIMETHYL-2,2'-BIPYRIDINE-N,N')MANGANESE(III) ACETONITRILE SOLVATE(1 1)/, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 180-181
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
2
Pages
180 - 181
Database
ISI
SICI code
0108-2701(1998)54:<180:(AS>2.0.ZU;2-N
Abstract
The structure of the title compound, [MnCl3(C12H12-N-2)]. CH3CN, consi sts of monomeric manganese(III) species with distorted trigonal bipyra midal geometry; Mn-N-ax 2.035 (1), Mn-N-eq 2.096 (1), Mn-Cl-ax 2.2187( 5), and Mn-Cl-eq 2.2587(5) and 2.3117 (5) Angstrom. The Mn complexes s tack as pairs in columns along the a axis, separated by columns of ace tonitrile. Spacing between the Mn-III atoms is not uniform and alterna ting distances of 6.704(1) (-x, -y, -z) and 7.713 (1) Angstrom (1-x, - y, -z) are observed.