A POLYMERIC NICKEL(II) THIOCYANATE COMPLEX OF N-(2-AMINOETHYL)-N-METHYL-1,2-ETHANEDIAMINE

Authors
NAYAK NP MUKHERJEE AK MONDAL A CHAUDHURI NR
Citation
Np. Nayak et al., A POLYMERIC NICKEL(II) THIOCYANATE COMPLEX OF N-(2-AMINOETHYL)-N-METHYL-1,2-ETHANEDIAMINE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 208-210
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
2
Pages
208 - 210
Database
ISI
SICI code
0108-2701(1998)54:<208:APNTCO>2.0.ZU;2-A
Abstract
The structure of [Ni(medien)(NCS)(mu-SCN)](n) [medien is N-(2-aminoeth yl)-N-methyl-1,2-ethanediamine, C5H15N3] is a polymeric chain with eac h pair of neighbouring nickel(II) ions linked by one SCN-bridging liga nd. The coordination polyhedron about the Ni-II atom is a distorted oc tahedron consisting of three N atoms of the medien ligand coordinating facially, one N atom of the non-bridging thiocyanate ligand, and one N and one S atom of two bridging thiocyanate ligands. The five-membere d chelate rings display envelope geometry.