YDRO-1-ANTHRYLAMINATO-N)(TRIPHENYLPHOSPHINE-P)GOLD

Authors
CHURAKOV AV KUZMINA LG HOWARD JAK
Citation
Av. Churakov et al., YDRO-1-ANTHRYLAMINATO-N)(TRIPHENYLPHOSPHINE-P)GOLD, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 212-214
Citations number
14
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
2
Pages
212 - 214
Database
ISI
SICI code
0108-2701(1998)54:<212:Y>2.0.ZU;2-A
Abstract
In the title compound, [Au(C14H8NO2)(C18H15P)],, the AuPPh3 group is l ocated at the amino group. The Au-N and Au-P distances are 2.019(3) an d 2.2420(8)Angstrom, respectively. The amino group H atom is involved in an intramolecular hydrogen bond with a carbonyl O atom. The bond-le ngth distribution in the aminoanthraquinone ligand is slightly differe nt from that in the free ligand, manifesting itself as a more pronounc ed contribution from the quinoid structure.