3-(ETA-3-ALLYL)-3,3-DICARBONYL-4-(DIMETHYL LFIDO)-3,1,2-MOLYBDADICARBA-CLOSO-DODECABORANE(12)

Authors
JOHANSEN K ROSAIR GM WELLER AS WELCH AJ
Citation
K. Johansen et al., 3-(ETA-3-ALLYL)-3,3-DICARBONYL-4-(DIMETHYL LFIDO)-3,1,2-MOLYBDADICARBA-CLOSO-DODECABORANE(12), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 214-217
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
2
Pages
214 - 217
Database
ISI
SICI code
0108-2701(1998)54:<214:3L>2.0.ZU;2-2
Abstract
The title charge-compensated allyl carbamolybdaborane 3)-C3H5)-3,3-(CO )(2)-4-SMe2-3,1,2-closo-MoC2B9H10, or [Mo(C3H5)(C4H16B9S)(CO)(2)], has been synthesized and its solid-state structure determined. In the sol id state, the conformation of the {Mo(eta(3)-C3H5)(CO)(2)} fragment is such that the carbonyl ligands are approximately trans to the cage C atoms and the conformation of the allyl group is exo.