High-resolution and high-S/N observations of the strong and relatively
narrow lambda 5797 diffuse interstellar absorption band, recorded wit
h the Ultra-High-Resolution Facility at the 3.9 m Anglo-Australian Tel
escope and the 0.9 m coude feed of the Kitt Peak National Observatory,
are reported. For selected lines of sight and using resolving powers
of up to 600,000, a remarkable degree of intrinsic ultrafine structure
is found within the band. There exists an almost exact correspondence
between the structure in the spectra recorded toward mu Sgr, zeta Per
, and zeta Oph, including one particularly narrow component with a wid
th that is comparable to the widths of atomic and molecular absorption
lines along these lines of sight. The results provide a new and extre
mely exacting test against which theoretical or laboratory candidates
can be assessed, and they point to a new approach to studies of diffus
e band carrier distributions through their velocity signatures.