TRANSITION-METAL COMPOUNDS OF CHLOROPHENOLS - SYNTHESIS, CHARACTERIZATION AND SINGLE-CRYSTAL X-RAY STRUCTURES OF (N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE) BIS(2,4,6-TRICHLOROPHENOLATO)COBALT(II) AND BIS(N-METHYLIMIDAZOLE) BIS(2,6-DICHLOROPHENOLATO)COPPER(II)

Authors
BASTURKMEN M KISAKUREK D DRIESSEN W GORTER S REEDIJK J
Citation
M. Basturkmen et al., TRANSITION-METAL COMPOUNDS OF CHLOROPHENOLS - SYNTHESIS, CHARACTERIZATION AND SINGLE-CRYSTAL X-RAY STRUCTURES OF (N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE) BIS(2,4,6-TRICHLOROPHENOLATO)COBALT(II) AND BIS(N-METHYLIMIDAZOLE) BIS(2,6-DICHLOROPHENOLATO)COPPER(II), Inorganica Chimica Acta, 271(1-2), 1998, pp. 19-23
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
271
Issue
1-2
Year of publication
1998
Pages
19 - 23
Database
ISI
SICI code
0020-1693(1998)271:1-2<19:TCOC-S>2.0.ZU;2-B
Abstract
The single-crystal X-ray structures of a cobalt(II) compound and of; a copper(II) compound with chlorophenolates as anions show that the aro matic chlorides participate in the coordination of the metal ion. The respective chromophores Co[N2cisO2transCl2cis] and Cu[N2transO2transCl 2trans] have distorted octahedral geometries in agreement with their l igand-field spectra. (C) 1998 Elsevier Science S.A.