Fly ashes from three municipal solid waste (MSW) incinerators in Taiwa
n were collected and segregated into different fractions for determini
ng the physical and chemical properties and dioxin contents. Analysis
of ashes with each fraction indicated that fine particles had higher d
ioxin contents than large particles. Dioxin homologue components of as
hes generated from large-scale mass burn MSW incinerator were less tox
ic than that from small-scale batch incinerators, and contained less n
on-2,3,7,8 PCDD/Fs. Correlation analysis did not reveal a consistent t
rend between dioxins content and ashes' physical properties, while str
ong positive correlation was found between dioxins content and chlorid
e content. Positive correlation between dioxin content and heavy metal
s content such as copper and zinc in the fly ash was also established.
(C) 1998 Elsevier Science Ltd.