SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF TRICARBONYL 1-AZAHEXA-1,3,5-TRIENE IRON(0) COMPLEXES

Authors
TOSCANO RA ROSAS R HERNANDEZGALINDO MD ALVAREZTOLEDANO C GARCIAMELLADO O
Citation
Ra. Toscano et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF TRICARBONYL 1-AZAHEXA-1,3,5-TRIENE IRON(0) COMPLEXES, Transition metal chemistry, 23(2), 1998, pp. 113-116
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
23
Issue
2
Year of publication
1998
Pages
113 - 116
Database
ISI
SICI code
0340-4285(1998)23:2<113:SASCOT>2.0.ZU;2-U
Abstract
nesulfonyl-6-(diethylamino)-1-azahexa-1,3,5-triene and omethansulfonyl )-1,4-dihydropyridinyl]-6-(diethyl- amino)-1-azahexa-1,3,5-triene reac t with Fe-2 (CO)(9) to yield sigma-N, pi-tricarbonyl complexes. The `u nexpected' pi binding to the C(4) and C(5) carbon atoms of the 1-azahe xa-1,3,5-triene moiety, inferred by spectroscopic data, was confirmed by single crystal X-ray diffraction studies. The ligands are arranged around the central Fe atom as a trigonal bipyramid.