In this paper, the main factors influencing thermal conductivity of di
amond film were analyzed in theory. The thermal conductivity of diamon
d film was measured by means of the photothermal deflection method, Va
rious crystal structures of diamond films were obtained by synthesis w
ith various deposition methods and conditions. Diamond films synthesiz
ed under lower concentration of methane and technique of annealing by
MWPCVD method have higher thermal conductivity. Thermal conductivity o
f diamond film increases with the increasing of removal thickness for
the SiC layer on the back of the film. (100)-oriented diamond thick fi
lms have higher thermal conductivity. (C) 1997 Elsevier Science S.A.