IMIDAZOLINIMINATO COMPLEXES OF TITANIUM - SYNTHESES AND X-RAY STRUCTURES OF [IMNTICL(3)](2) AND [IMNTICL(3)CENTER-DOT-2MECN] (IMN EQUALS 1,3-IMIDAZOLIN-2-IMINO)

Authors
KUHN N FAWZI R STEIMANN M WIETHOFF J
Citation
N. Kuhn et al., IMIDAZOLINIMINATO COMPLEXES OF TITANIUM - SYNTHESES AND X-RAY STRUCTURES OF [IMNTICL(3)](2) AND [IMNTICL(3)CENTER-DOT-2MECN] (IMN EQUALS 1,3-IMIDAZOLIN-2-IMINO), Zeitschrift fur anorganische und allgemeine Chemie, 623(5), 1997, pp. 769-774
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
5
Year of publication
1997
Pages
769 - 774
Database
ISI
SICI code
0044-2313(1997)623:5<769:ICOT-S>2.0.ZU;2-F
Abstract
1,3-Dimethyl-2-trimethylsilyiminoimidazolin (ImNSiMe(3), 7) reacts wit h TiCl4 in n-pentane to give the dinuclear complex [(ImN)TiCl3](2) (8) which is transferred into the mononuclear compound [(ImN)TiCl3 . 2MeC N] (9) on treatment with acetonitrile. The X-ray structure analyses de monstrate the strong donor ability of the imidazoliniminato substituen t both in the terminal and bridging coordination mode similar to that of the phosphaniminato group R3PN.