EXCESS MOLAR VOLUMES AND KINEMATIC VISCOSITIES OF BINARY-LIQUID MIXTURES OF CYCLOHEXANONE PLUS DICHLOROMETHANE, PLUS TRICHLOROMETHANE, PLUS1,2-DICHLOROETHANE, PLUS TRICHLOROETHENE, PLUS 1,1,1-TRICHLOROETHANE,AND PLUS CYCLOHEXANE
J. Nath et Sk. Mishra, EXCESS MOLAR VOLUMES AND KINEMATIC VISCOSITIES OF BINARY-LIQUID MIXTURES OF CYCLOHEXANONE PLUS DICHLOROMETHANE, PLUS TRICHLOROMETHANE, PLUS1,2-DICHLOROETHANE, PLUS TRICHLOROETHENE, PLUS 1,1,1-TRICHLOROETHANE,AND PLUS CYCLOHEXANE, Journal of chemical and engineering data, 43(2), 1998, pp. 196-200
Excess molar volumes, V-m(E), at T = 298.15 K, and kinematic viscositi
es, v, at T = 303.15 K, have been measured for binary liquid mixtures
of cyclohexanone (C6H10O) + dichloromethane (CH2Cl2), + trichlorometha
ne (CHCl3), + 1,2-dichloroethane (CH2ClCH2Cl), + trichloroethene (CHCl
CCl2), + 1,1,1-trichloroethane (CCl3CH3), and + cyclohexane (c-C6H12)
The values of v and V-m(E) have been fitted in appropriate equations u
sing a least-squares method. VE,has been found to be negative througho
ut the entire range of composition for mixtures of C6H10O + CH2Cl2, CHCl3, + CHClCCl2, and + CCl3CH3, and positive for C6H10O + c-C6H12. F
or C6H10O + CH2ClCH2Cl, V-m(E) has been found to be positive at lower
mole fractions of C6H10O, and negative at higher mole fractions. The a
nalysis has shown that McAllister's approach correlates v of the prese
nt mixtures throughout the entire composition range to a significantly
high degree of accuracy.