X-RAY STRUCTURE AND RAMAN-SPECTRUM OF O)(2)(MU-2-(OPR)-PR-I)(2)((OPR)-PR-I)(8)(ACAC)(2)] - PRESENCE OF A TI-4(MU(3)-O)(2)(MU(2)-(OPR)-PR-I)(2) LADDER-LIKE CORE

Authors
MORAN PD RICKARD CEF BOWMAKER GA COONEY RP BARTLETT JR WOOLFREY JL
Citation
Pd. Moran et al., X-RAY STRUCTURE AND RAMAN-SPECTRUM OF O)(2)(MU-2-(OPR)-PR-I)(2)((OPR)-PR-I)(8)(ACAC)(2)] - PRESENCE OF A TI-4(MU(3)-O)(2)(MU(2)-(OPR)-PR-I)(2) LADDER-LIKE CORE, Inorganic chemistry, 37(6), 1998, pp. 1417
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
6
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:6<1417:XSAROO>2.0.ZU;2-2
Abstract
The partial hydrolysis of titanium tetraisopropoxide in the presence o f acetylacetone yields the complex )(2)(mu(2)-(OPr)-Pr-i)(2)((OPr)-Pr- i)(8)(acac)(2)] in which c)((OPr)-Pr-i)(2)TiO((OPr)-Pr-i)Ti((OPr)-Pr-i )(2)] units are linked into dimers via the bridging oxide ion to form a ladder-like Ti-4(mu(3)-O)(2)(mu(2)-(OPr)-Pr-i)(2) core containing fi ve-and six-coordinate titanium and three-coordinate oxide ions that li nk the two units together through bonds to the five-coordinate titaniu m atoms. The Raman spectrum shows bands at 521 and 712 cm(-1) that are assigned to nu(Ti-O) modes of bridging isopropoxide ligands and the m u(3)-oxygen, respectively.