REACTIONS OF 6,9-BIS(DIMETHYL SULFIDE)DECABORANE(14), 6,9-[(CH3)(2)S](2)B10H12 - MECHANISTIC CONSIDERATIONS

Authors
BEALL H GAINES DF
Citation
H. Beall et Df. Gaines, REACTIONS OF 6,9-BIS(DIMETHYL SULFIDE)DECABORANE(14), 6,9-[(CH3)(2)S](2)B10H12 - MECHANISTIC CONSIDERATIONS, Inorganic chemistry, 37(6), 1998, pp. 1420
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
6
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:6<1420:RO6S6>2.0.ZU;2-H
Abstract
The deuterium-labeled 6,9-[(CH3)(2)S](2)-2,4-D2B10H10 is formed regios pecifically from 2,4-D2B10H12 and (CH3)(2)S. Likewise, the deuterium l abels are retained in the same relative locations when 6,9-[(CH3)(2)S] (2)-2,4-D2B10H10 is converted to 5-[(CH3)2S]-2,4-D2B10H10, by thermal ligand displacement, and to 5-[(CH3)(2)S]-9-(Thx)-2,4-D2B10H9 by hydro boration of 2,3-dimethyl-2-butene.