SYNTHESES OF TITANIUM AND ZIRCONIUM CHLOROTRIALKYL COMPLEXES AND CRYSTAL-STRUCTURE OF CHLOROTRINEOPENTYLZIRCONIUM CONTAINING UNUSUAL LINEARSYMMETRICAL METAL-CHLORIDE POLYMERIC CHAINS

Authors
MCALEXANDER LH LI LT YANG YH POLLITTE JL XUE ZL
Citation
Lh. Mcalexander et al., SYNTHESES OF TITANIUM AND ZIRCONIUM CHLOROTRIALKYL COMPLEXES AND CRYSTAL-STRUCTURE OF CHLOROTRINEOPENTYLZIRCONIUM CONTAINING UNUSUAL LINEARSYMMETRICAL METAL-CHLORIDE POLYMERIC CHAINS, Inorganic chemistry, 37(6), 1998, pp. 1423
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
6
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:6<1423:SOTAZC>2.0.ZU;2-3
Abstract
Chlorotrineopentylzirconium (Me3CCH2)(3)ZrCl was found to crystallize in polymeric chains with unusual linear and symmetric chloride bridges and the repeat unit -Cl-Zr(CH2CMe3)(3)-Cl-Zr(CH2CMe3)(3)-. The synthe ses of new trialkyl chloride complexes (Me-3-SiCH2)(3)MCl (M = Ti, Zr) and improved methods of preparing (Me3CCH2)(3)MCl (M = Ti, Zr) and te traalkyl complexes (Me3ECH2)(4)Ti (E = C, Si) are reported.