H. Casabianca et al., ENANTIOMERIC DISTRIBUTION STUDIES OF LINALOOL AND LINALYL ACETATE - APOWERFUL TOOL FOR AUTHENTICITY CONTROL OF ESSENTIAL OILS, HRC. Journal of high resolution chromatography, 21(2), 1998, pp. 107-112
The enantiomeric distributions of linalool and linalyl acetate in vari
ous natural products are measured by enantioselective gas chromatograp
hy on alkyl-substituted cyclodextrins. Different plant cultivars were
investigated by four extraction processes: steam distillation, solvent
extraction, supercritical fluid extraction, and headspace analysis, C
areful attention must be paid to linalool which undergoes partial race
mization under certain processing conditions. In most cases, enantiome
ric distribution is a powerful tool for authenticity testing.