PALLADIUM-CATALYZED REACTIONS OF ALLENES, CARBON-MONOXIDE AND NUCLEOPHILES

Authors
GRIGG R MONTEITH M SRIDHARAN V TERRIER C
Citation
R. Grigg et al., PALLADIUM-CATALYZED REACTIONS OF ALLENES, CARBON-MONOXIDE AND NUCLEOPHILES, Tetrahedron, 54(15), 1998, pp. 3885-3894
Citations number
43
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
15
Year of publication
1998
Pages
3885 - 3894
Database
ISI
SICI code
0040-4020(1998)54:15<3885:PROACA>2.0.ZU;2-U
Abstract
Hydridopalladium(II) species generated in situ by oxidative addition o f Pd(0) to acetic acid or acidic hydroxyl substrates (phenols, oximes) catalyse the termolecular assembly of allenes, CO and amines (primary , secondary) or oxygen nucleophiles to give methacrylamides or methacr ylate esters and derivatives thereof in good to excellent yield. (C) 1 998 Elsevier Science Ltd. All rights reserved.