Be. Nesbitt et K. Muehlenbachs, PALEO-HYDROGEOLOGY OF LATE PROTEROZOIC UNITS OF SOUTHEASTERN CANADIANCORDILLERA, American journal of science, 297(4), 1997, pp. 359-392
A comprehensive geological and geochemical investigation of veining an
d other manifestations of fluid flow in late Proterozoic units of the
Windermere Supergroup in the southeastern Canadian Cordillera was unde
rtaken to characterize the nature of hydrogeological systems during an
d following deformation of a fold and thrust belt. The results of flui
d inclusion studies document vein formation from moderate to low tempe
rature, low salinity, aqueous fluids. Results of delta(18)O studies of
vein quartz and carbonate indicate that the veins formed from fluids
with high delta(18)O values, which in most cases were derived from ext
ensive isotopic exchange between the fluids and Proterozoic units. In
widespread, small, early, bedding-parallel veins and in larger subvert
ical veins in units of biotite greenschist or higher metamorphic grade
s, delta D values of inclusion fluids are generally > -90 permil indic
ating vein formation from fluids originating from metamorphic devolati
lization. In rocks of metamorphic grade less than biotite greenschist
facies, larger, late tectonic, subvertical veins have delta D values (
-120 to -150 permil) for inclusion fluids indicative of vein formation
from deeply circulated meteoric water. Results of delta(13)C and Sr-8
7/Sr-86 studies of vein carbonates indicate a marked degree of regiona
l heterogeneity, which is related to variations in the host rock litho
logy. Most significant are the unusually low delta(13)C (-11 to -17 pe
rmil) and high Sr-87/Sr-86 (0.750 to 0.780) values of vein carbonate f
rom the Old Fort-Point Formation. The close linkage of the delta(13)C
and Sr-87/Sr-86 values of vein carbonate to lithology of the host unit
indicates relatively rapid reequilibration of the isotopic signatures
of dissolved C and Sr, as the fluids moved from one unit to another.
Comparison of the results of this study to results obtained on a simil
ar study of paleo-hydrogeology of extensional regimes of the southern
Omineca Belt of the Canadian Cordillera indicates that in compressiona
l regimes the depth of penetration of surface fluids is shallower and
more heterogeneous. As a result, convected surface fluids in compressi
onal regimes are in general cooler, have lower CO2 contents, and proba
bly lower integrated total fluxes.