A. Bekkerman et al., DIRECT EXPERIMENTAL-EVIDENCE FOR THE THERMAL NATURE OF DELAYED ELECTRON-EMISSION FROM A SUPERHOT C-60 MOLECULE, The Journal of chemical physics, 108(13), 1998, pp. 5165-5168
Delayed electron emission from superhot neutral C-60 was found to stro
ngly depend on the initial molecular thermal energy. This dependence i
s clearly demonstrated by measurements of delayed ionization efficienc
y curves following electron impact for widely different C-60 average v
ibrational energies in the range of 8-14 eV. These measurements provid
e direct experimental evidence for the thermal nature of delayed ioniz
ation of superhot clusters. A simulation based on decay kinetics with
thermal rate constants was found to be in good agreement with experime
nt. (C) 1998 American Institute of Physics.