POTASSIUM HYDRIDE AS NUCLEOPHILE - A PRACTICAL METHOD FOR CLEAVAGE AND FUNCTIONAL MODIFICATION OF CR(CO)(3)-AR-SIME3 BONDS

Authors
MANDAL SK SARKAR A
Citation
Sk. Mandal et A. Sarkar, POTASSIUM HYDRIDE AS NUCLEOPHILE - A PRACTICAL METHOD FOR CLEAVAGE AND FUNCTIONAL MODIFICATION OF CR(CO)(3)-AR-SIME3 BONDS, Journal of organic chemistry, 63(6), 1998, pp. 1901-1905
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
63
Issue
6
Year of publication
1998
Pages
1901 - 1905
Database
ISI
SICI code
0022-3263(1998)63:6<1901:PHAN-A>2.0.ZU;2-D
Abstract
Potassium hydride reacts with Cr(CO)(3)-aryltrimethylsilanes at roam t emperature to generate stabilized aryl anions which can further react with electrophiles.