FE2O3 FILMS CHI((3)) OPTICS - RAMAN AND XAS CHARACTERIZATION

Citation
P. Lottici et al., FE2O3 FILMS CHI((3)) OPTICS - RAMAN AND XAS CHARACTERIZATION, Optical materials, 9(1-4), 1998, pp. 368-372
Citations number
10
Categorie Soggetti
Material Science",Optics
Journal title
ISSN journal
09253467
Volume
9
Issue
1-4
Year of publication
1998
Pages
368 - 372
Database
ISI
SICI code
0925-3467(1998)9:1-4<368:FFCO-R>2.0.ZU;2-R
Abstract
Two different sol-gel syntheses, both starting from inorganic salts as precursors, Fe(NO3)(3) . 9H(2)O or FeCl3 . 6H(2)O, have been employed to prepare, by dip-coating, films of alpha-Fe2O3, which are currently investigated for their high non-linear optical susceptibility chi((3) ). Thermal treatments at 500 degrees C lend to the alpha-Fe2O3 hematit e structure for both preparations as indicated by XRD and Raman. Infor mation on the differences in the local order between the two preparati ons are obtained by X-ray absorption spectroscopy (XAS) measurements. (C) 1998 Elsevier Science B.V.