Two different sol-gel syntheses, both starting from inorganic salts as
precursors, Fe(NO3)(3) . 9H(2)O or FeCl3 . 6H(2)O, have been employed
to prepare, by dip-coating, films of alpha-Fe2O3, which are currently
investigated for their high non-linear optical susceptibility chi((3)
). Thermal treatments at 500 degrees C lend to the alpha-Fe2O3 hematit
e structure for both preparations as indicated by XRD and Raman. Infor
mation on the differences in the local order between the two preparati
ons are obtained by X-ray absorption spectroscopy (XAS) measurements.
(C) 1998 Elsevier Science B.V.