We have investigated the effect of argon excimer laser irradiation of
silicon nitride films deposited on silicon substrates. When the film t
hickness is equal to or greater than 40 nm, the irradiation induces am
orphous silicon precipitation near the thin surface layer of the film,
which has been clarified by means of x-ray photoelectron and Raman sp
ectroscopy. The formation mechanism of amorphous silicon with the irra
diation is discussed. The phase of silicon precipitation depends on th
e thermal properties of the substrate material. (C) 1998 American Inst
itute nf Physics. [S0021-8979(98)04507-1].